Lutetium, Lu, atomic number 71
General
Lutetium is a chemical element with the element symbol Lu and the atomic number 71. In the periodic table it is in the group of lanthanides and thus also belongs to the metals of the rare earths.
Lutetium was discovered by 1905 independently by three scientists: Carl Auer von Welsbach, Charles James and the Frenchman Georges Urbain, who named it after the Roman name of Paris, Lutetia. In the German-speaking world it was until 1949 usually referred to as Cassiopeium (chemical symbol Cp).
In nature, lutetium occurs only in compounds. Low-concentration lutetium-containing minerals are:
Monazite (Ce, La, Th, Nd, Y) PO4 (Lu content <0,01%)
Recovery
After a complex separation of the other Lutetiumbegleiter the oxide is reacted with hydrogen fluoride to Lutetiumfluorid. Subsequently, this is reduced with calcium to form metallic lutetium with the formation of calcium fluoride. Separation of remaining calcium residues and impurities takes place in an additional remelting in vacuo.
Features
The silver-gray metal is very soft, well stretchable and malleable. In dry air lutetium is quite stable, in moist air it turns gray. At higher temperatures, it burns to the sesquioxide Lu2O3. With water, it reacts very slowly with evolution of hydrogen to the hydroxide. In mineral acids, it dissolves to form hydrogen.
In its compounds it is present in the oxidation state + 3, the Lu3 + cations form colorless solutions in water.
Usage
Lutetium is used in scintillator crystals for positron emission tomography. One of the most prominent examples is cerium-doped lutetium oxyorthosilicate (LSO). The radionuclide 177Lu can be used as a therapy against neuroendocrine tumors.
No biological function has yet been found for lutetium.
Lutetium and lutetium compounds are low in toxicity. The metal dusts are flammable and explosive, like many others.
General | |
Name, symbol
ordinal |
Lutetium, Lu, 7167 |
Series | lanthanides |
Group, period, block | La, 6, f |
Appearance | silvery white |
CAS number | 7439-94-3 |
Mass fraction of the earth's envelope | 0,7 ppm |
Atomic | |
atomic mass | 174,967 u |
atomic radius | 175 pm |
Covalent radius | 187 pm |
Elektronenkonf. | [Xe] 4f (14) 5d (1) 6s2 |
1. ionization | 523,5 KJ / mol |
2. ionization | 1340 KJ / mol |
3. ionization | 2022,3 KJ / mol |
Physically | |
Physical state | fixed |
crystal structure | hexagonal |
density | 9,84 g / cm3 (25 ° C) |
magnetism | paramagnetic (χm = 0,0) |
melting point | 1925 K (1652 C) |
boiling point | 3675 K (3402 C) |
Molar volume | 17,78 * 10 (-6) m (3) / mol |
Heat of vaporization | 415 KJ / mol |
heat of fusion | 22,0 KJ / mol |
Electric conductivity | 1,72 * 10 (6) A / (V * m) |
thermal conductivity | 16 W / (m * K) |