Ytterbium

Ytterbium, Yb, atomic number 70

General

Ytterbium [ʏtɛrbiʊm] is a chemical element with the element symbol Yb and the ordinal number 70. In the periodic table it is in the group of lanthanides and thus also belongs to the metals of the rare earths. Ytterbium is named after the first site, the Ytterby mine near Stockholm, as well as yttrium, terbium and erbium.
Ytterbium (derived from Ytterby, a pit on an archipelago north of Stockholm, which was also the name of the elements yttrium, terbium and erbium godfather) 1878 was discovered by the Swiss chemist Jean Charles Galissard de Marignac. Marignac found a new ingredient in the soil known as Erbia and called it Ytterbia. He suspected in the compound isolated from him a new element, which he called Ytterbium. 1907 separated French chemist Georges Urbain Marignacs Ytterbia into two components, Neoytterbia and Lutetia. Carl Auer von Welsbach also worked at the same time with Ytterbia and called the two components Aldebaranium and Cassiopeium. Later, the element name Neoytterbium was shortened to Ytterbium. The pure metal was 1937 by Klemm and Bonner represented by the reduction of YbF3 with potassium. The determination of the physical and chemical properties of the element ytterbium could only be done 1953 after production of the pure metal.

Ytterbium metal

Ytterbium metal

Recovery

After extensive separation of the other ytterbium companions, the oxide is reduced with lanthanum to metallic ytterbium. Then the ytterbium is sublimated.

Chart Ytterbium oxide 2010-2012

Chart Ytterbium oxide 2010-2012

Features

The silvery white metal is very elastic and soft. It forms three allotropic modifications with conversion points at -13 ° C and 795 ° C. At room temperature, β-ytterbium forms a face-centered cubic lattice, at higher temperatures a cubic-body centered lattice. At a pressure of 16.000 bar, β-Yb shows semiconductor properties in terms of electrical conductivity.
Ytterbium turns gray in dry air. At higher temperatures it burns to the sesquioxide Yb2O3. With water, it reacts slowly with evolution of hydrogen to the hydroxide. In mineral acids, it dissolves to form hydrogen. In its compounds it is usually in the oxidation number + 3 before, the Yb3 + cations form colorless solutions in water, Yb2 + cations green solutions.

Periodic Table Ytterium-70

Periodic Table Ytterium-70

Usage

Ytterbium can be used for grain refining and to improve the mechanical properties of stainless steels. The radioactive isotope 169Yb (half-life 32 days) is occasionally used as a source of γ-radiation in nuclear medicine.
Ytterbium-cobalt-iron-manganese alloys are suitable for high-quality permanent magnets.
Ytterbium-doped crystals (mainly Yb: YAG) are used as reinforcing material in lasers.
Ytterbium is not very toxic. Metal dusts are fire and explosive.

General
Name, symbol

ordinal

Ytterbium, Yb, 70
Series lanthanides
Group, period, block La, 6, f
Appearance silvery white
CAS number 7440-64-4
Mass fraction of the earth's envelope 2,5 ppm
Atomic
atomic mass 173,04 u
atomic radius 175 pm
Covalent radius 187 pm
Elektronenkonf. [Xe] 4f (14) 6s2
1. ionization 603,4 KJ / mol
2. ionization 1174,8 KJ / mol
3. ionization 2417 KJ / mol
Physically
Physical state fixed
crystal structure Cubic area-centered
density 6,973 g / cm3 (25 ° C)
magnetism paramagnetic (χm = 3,4 * 10 (-5))
melting point 1097 K (824 C)
boiling point 1469 K 1196 C)
Molar volume 24,84 * 10 (-6) m (3) / mol
Heat of vaporization 160 KJ / mol
heat of fusion 7,7 KJ / mol
Electric conductivity 4,0 * 10 (6) A / (V * m)
thermal conductivity 39 W / (m * K)

Prices for Ytterbium -> Prices for Rare Earths - Ytterbium

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